Category: 6413-10-1

Highly efficient heterogeneous procedure for the synthesis of fructone fragrancy was written by Gao, Shan;Liang, Xue Zheng;Yang, Jian Guo;He, Ming Yuan. And the article was included in Science in China, Series B: Chemistry in 2008.Category: dioxole The following contents are mentioned in the article:

A novel heterogeneous strong acid catalyst was synthesized through the copolymerization of p-toluenesulfonic acid and paraformaldehyde and utilized for the synthesis of fructone. The results showed that the catalyst was very efficient for the reaction with the yield over 95%. The advantages of extremely high d. of acidity, high thermal and chem. stability, low cost for the simple synthetic procedure, and reusability made the catalyst one of the best choices for the reaction. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Category: dioxole).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Category: dioxole

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Efficient and straightforward preparation of a building block for (-)-teubrevin G synthesis via chemically diverse oriented synthesis was written by Velazquez, Daniel Garcia;Luque, Rafael. And the article was included in Tetrahedron Letters in 2011.Reference of 6413-10-1 The following contents are mentioned in the article:

A rapid and efficient methodol. to highly functionalized mol. units well suited as scaffolds for diversity-oriented mol. construction in the synthesis of natural products was reported. A key macrocyclic intermediate I in the synthesis of the neo-clerodane diterpene (-)-teubrevin G was successfully synthesized in a 5-step sequence in a 70% overall yield using a novel intramol. coupling between an allylborating agent and a 1,5-dialdehyde moiety. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Reference of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Reference of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis of new efficient laser dyes of red spectral range, the DCM analogs, based on 2-aryl-6-methyl-4H-pyrone was written by Ponomareva, O. V.;Lugovskii, A. P.;Lugovskii, A. A.;Males, M. P.;Komlev, I. V.;Nifant’ev, E. E.. And the article was included in Russian Journal of General Chemistry in 2011.Recommanded Product: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

A new method was developed for the synthesis of 2-aryl-6-methyl-4H-pyrones by the condensation of arylmethylketones with the acetoacetic ester ethylene ketal in the presence of sodium alkoxylate. New laser merocyanine dyes, the analogs of 4-dicyanomethylene-2-methyl-6-[(4-dimethylamino)styryl]-4H-pyran (DCM), were obtained based on the synthesized 2-aryl-4-pyrones. The dyes are characterized by high generation efficiency in the red spectral range. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Recommanded Product: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Recommanded Product: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Preparation of fructone using copper methanesulfonate as catalyst was written by Peng, Anshun;Chen, Changxing. And the article was included in Riyong Huaxue Gongye in 2005.Category: dioxole The following contents are mentioned in the article:

Fructone (i.e., 2-methyl-1,3-dioxolane-2-acetic acid Et ester) was synthesized using Et acetoacetate and glycol as starting materials and copper methanesulfonate as catalyst. Factors influencing the yield were examined by the orthogonal experiments The optimum conditions were as follows: n(Et acetoacetate)/n(glycol) 1:1.5, catalyst dosage 7.5 g, water carrying agent 7.5 mL, reaction under reflux condition for 3 h. The yield can achieve 88.2%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Category: dioxole).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Category: dioxole

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Highly efficient procedure for the synthesis of fructone fragrance using a novel carbon based acid was written by Hu, Baowei;Li, Chunqing;Zhao, Sheng-Xian;Rong, Lin-Mei;Lv, Shao-Qin;Liang, Xuezheng;Qi, Chenze. And the article was included in Molecules in 2010.Recommanded Product: 6413-10-1 The following contents are mentioned in the article:

A highly efficient synthesis of fructone in yields over 95% has been developed using the novel carbon based acid, obtained via one-step hydrothermal carbonization of furaldehyde and hydroxyethylsulfonic acid, as catalyst. The advantages of the catalyst are high activity, stability, reusability, low cost and simplicity of synthesis, and applicability to the reactions of various diols with β-keto esters. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Recommanded Product: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Recommanded Product: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis of fructone catalyzed by iodine/silica composite was written by Yin, Jie;Bai, Wenhua;Liu, Wanyi;Tian, Jumei;Cai, Lei. And the article was included in Shiyou Huagong Yingyong in 2006.COA of Formula: C8H14O4 The following contents are mentioned in the article:

Fructone was synthesized from Et acetoacetate (1) and glycol (2) using I₂/SiO₂ (3) as catalyst. Factors influencing the yield were discussed and the best conditions were found. The results showed that 3 was an excellent catalyst, with n (1):n (2)=1.0:1.7, w (3)=0.9%, and reaction time 90 min, the yield of fructone can reach 88.8%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1COA of Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis and application of fructone was written by Tang, Jian. And the article was included in Dangdai Huagong in 2009.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

The phys. and chem. properties and aroma characteristic of fructone were outlined. Using citric acid as catalyst, fructone was synthesized by the condensed carbonylation of Et acetoacetate and 1,2-ethanediol. The application of fructone in flavor was studied. It is seen that in the future that fructone will be more and more widely used in flavor. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Polysubstituted Oxygen Heterocycles by a Reformatsky-Type Reaction/Reductive Cyclization Approach from Enantiopure β-Ketosulfoxides was written by Colobert, Francoise;Choppin, Sabine;Ferreiro-Mederos, Leticia;Obringer, Michel;Luengo Arratta, Sandra;Urbano, Antonio;Carreno, M. Carmen. And the article was included in Organic Letters in 2007.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

The stereoselective synthesis of tetrasubstituted tetrahydrofurans and trisubstituted tetrahydropyrans bearing a sulfoxide moiety was achieved by reductive cyclization (Et₃SiH/TMSOTf) of the corresponding enantiopure hydroxy ketones protected as dioxolanes. The latter are easily accessible from a Reformatsky-type reaction between α-bromo-α’-sulfinyl ketones and protected α- or β-ketoaldehydes, followed by diastereoselective reduction of the resulting β-ketosulfoxide. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.HPLC of Formula: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Chemical components and insecticidal activity of essential oil in Periploca sepium root bark to Schizaphis graminum was written by Shi, Qinghua;Ma, Yangmin;Qin, Huqiang. And the article was included in Xibei Zhiwu Xuebao in 2006.Electric Literature of C8H14O4 The following contents are mentioned in the article:

Chem. components of essential oil in Periploca sepium root bark were determined by gas chromatog.-mass spectrometer and 15 compounds were isolated. Ten of the compounds were identified as 4-methoxysalicylaldehyde, Bu acetate, 2-methyl-1,3-dioxycyclopentyl acetate, S-[-8-(diethylphosphono)octyl]-ethanethioate, 1,1,3,3,-tetrabutoxy-2-propanone, 4-methyl-2-pentanone, Bu formate, 1-(1-ethoxyethoxy)-butane, and 2-butoxytetrahydropyran, and n-Bu ether, which accounted for 94.91% of the essential oil. The insecticidal activity of the essential oil was tested with Schizaphis graminum and the test results indicated that the essential oil had strong insecticidal activity to the test insect. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Electric Literature of C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Electric Literature of C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Ionic liquid mediated aluminum sulfate: highly effective catalyst for synthesis of the acetalization reaction was written by Lin, Qi;Zheng, Huirong;Wang, Liwei;Chen, Yiting. And the article was included in Advanced Materials Research in 2012.Application of 6413-10-1 The following contents are mentioned in the article:

The acetalization reaction of Et acetoacetate (EAA) with 1,2-propanediol (PPO) was performed efficiently in ionic liquid using aluminum sulfate as catalyst. The synergistic effect between aluminum sulfate and ionic liquid [bmim]BF4 on the acetalization was observed An EAA conversion of 89.6% with the fructone selectivity of above 99.0% was achieved under the optimized reaction conditions. After the reaction was completed, the products could be easily separated from the reaction mixture extracted by di-Me ether, and the catalyst and ionic liquid could be directly recycled several times without a significant decrease in the activity and selectivity towards fructone. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Application of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Application of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem