Efficient and straightforward preparation of a building block for (-)-teubrevin G synthesis via chemically diverse oriented synthesis was written by Velazquez, Daniel Garcia;Luque, Rafael. And the article was included in Tetrahedron Letters in 2011.Reference of 6413-10-1 The following contents are mentioned in the article:
A rapid and efficient methodol. to highly functionalized mol. units well suited as scaffolds for diversity-oriented mol. construction in the synthesis of natural products was reported. A key macrocyclic intermediate I in the synthesis of the neo-clerodane diterpene (-)-teubrevin G was successfully synthesized in a 5-step sequence in a 70% overall yield using a novel intramol. coupling between an allylborating agent and a 1,5-dialdehyde moiety. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Reference of 6413-10-1).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Reference of 6413-10-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem