Tag: 142.1956

Liu, Taotao et al. published their research in RSC Advances in 2014 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Recommanded Product: 1,4-Dioxaspiro[4.5]decane

Zeolite nanofiber assemblies as acid catalysts with high activity for the acetalization of carbonyl compounds with alcohols was written by Liu, Taotao;Fu, Wenqian;Zheng, Xiang;Jiang, Jun;Hu, Maolin;Tang, Tiandi. And the article was included in RSC Advances in 2014.Recommanded Product: 1,4-Dioxaspiro[4.5]decane This article mentions the following:

Zeolite nanofiber assemblies (HNB-MOR) as efficient heterogeneous catalysts for the formation of a range of acetals in good yields. The mesoporosity of HNB-MOR benefits mass transfer, and the strong acidic sites on HNB-MOR facilitate acetalization activity. The catalyst can be reused 10 times without loss of activity. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Recommanded Product: 1,4-Dioxaspiro[4.5]decane).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Recommanded Product: 1,4-Dioxaspiro[4.5]decane

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Lu, Ting et al. published their research in Journal of Solid State Chemistry in 2017 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Formula: C8H14O2

Four Strandberg-type polyoxometalates with organophosphine centre decorated by transition metal-2,2′-bipy/H2O complexes was written by Lu, Ting;Feng, Shu-Li;Zhu, Zai-Ming;Sang, Xiao-Jing;Su, Fang;Zhang, Lan-Cui. And the article was included in Journal of Solid State Chemistry in 2017.Formula: C8H14O2 This article mentions the following:

Four inorganic-organic hybrid compounds composed of Strandberg-type organophosphomolybdate anion [(C6H5PO3)2Mo5O15]4- (abbreviated as (PhP)2Mo5) and transition metal (TM)-2,2′-bipy/H2O complex units, namely [(TM(H2O)(bipy))2(C6H5PO3)2Mo5O15]n (TM = Co, (1); Ni, (2)), [(Cu(bipy)2)2(C6H5PO3)2Mo5O15]·2H2O (3) and [(Zn(bipy)(μ-OH))2(Zn(bipy)2(C6H5PO3)2Mo5O15)2]·3H2O (4) (bipy = 2,2′-bipyridine), were successfully constructed under hydrothermal conditions, and their structures were determined by single crystal x-ray diffraction anal. and spectroscopic methods. The central heteroatoms in these polyoxometalates (POMs) are all organophosphine (RP) groups. Compound 1 and compound 2 are isostructural (PhP)2Mo5-based TM-coordination polymers with the two-dimensional layer frameworks. In compound 3, the bi-supporting structure containing one (PhP)2Mo5 unit and two [Cu(bipy)2]2+ cations. For compound 4, it can be regarded as a dimer of two bi-supporting {Zn(bipy)2(PhP)2Mo5Zn(bipy)} clusters that were connected by two μ-OH groups. The acid-catalytic activities and fluorescence properties of the four hybrids have been investigated. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Formula: C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Formula: C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Kandasamy, Sabariswaran et al. published their research in Biomass and Bioenergy in 2019 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Reference of 177-10-6

Hydrothermal liquefaction of microalgae using Fe3O4 nanostructures as efficient catalyst for the production of bio-oil: Optimization of reaction parameters by response surface methodology was written by Kandasamy, Sabariswaran;Zhang, Bo;He, Zhixia;Chen, Haitao;Feng, Huan;Wang, Qian;Wang, Bin;Bhuvanendran, Narayanamoorthy;Esakkimuthu, Sivakumar;Ashokkumar, Veeramuthu;Krishnamoorthi, M.. And the article was included in Biomass and Bioenergy in 2019.Reference of 177-10-6 This article mentions the following:

The aim of the present work was focused on optimizing the hydrothermal liquefaction (HTL) of Spirulina platensis catalyzed by Fe3O4 nanostructures to enhance the bio-oil yield and quality of bio-oil using response surface methodol. (RSM). The structural morphol. and crystalline nature of the synthesized catalyst was determined using a scanning electron microscope (SEM), high resolution transmission electron microscopy (HR-TEM) and X-ray powder diffraction (XRD). Three of the vital reaction parameters such as temperature, holding time and catalyst dosage were optimized through central composite design. A maximum bio-oil yield of 32.33% was observed for the high temperature at 320°C, 0.75 g of catalyst dosage and 37 min of resident time. The maximum conversion was found at a lower temperature of 272°C, the bio-oil yield of 27.66% was obtained with 0.45 g of catalyst dosage and 24 min of holding time which is an energy efficient optimum condition. The maximum bio-oil yield was influenced at a lower temperature due to the high catalytic activity. While compared to higher temperatures were not much influence was observed It clearly states that the catalyst dosage playing a critical role in the lower temperature HTL reaction. GC-MS and FT-IR anal. of the produced bio-oil exhibits significant characteristics for biofuel applications. The Fe3O4 catalyst was recyclable for up to eight repeated cycles and constant bio-oil yield for the last four cycles. It shows the excellent reproduction ability towards HTL of Spirulina sp. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Reference of 177-10-6).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Reference of 177-10-6

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Chen, Wen-long et al. published their research in Guangzhou Huagong in 2016 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Electric Literature of C8H14O2

Preparation and catalytic application of SO42-/SnO2-WO3/KIT-6 complex solid acid was written by Chen, Wen-long;Liang, Xi-xi;Xu, Xue-qing;Lei, Cheng;Jia, Na;Yang, Zhi-wang. And the article was included in Guangzhou Huagong in 2016.Electric Literature of C8H14O2 This article mentions the following:

Complex solid acid of SO42-/SnO2-WO3/KIT-6 was prepared through impregnation method using KIT-6 as template. The solid acid was used as catalyst for the Baeyer-Villiger oxidation of cyclic ketones and the condensation reaction between ketones/aldehyde and diols. It was found that the synthesized solid acid exhibited promising catalytic activity in the two kinds of reactions. The introducing of the WO3 and KIT-6 increased not only the acidity but also the specific area of the solid acid, therefore, the catalytic activity of the solid acid was enhanced. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Electric Literature of C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Electric Literature of C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Benohoud, Meryem et al. published their research in Chemistry – A European Journal in 2011 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 177-10-6

Stereoselective Hydrosilylation of Enals and Enones Catalysed by Palladium Nanoparticles was written by Benohoud, Meryem;Tuokko, Sakari;Pihko, Petri M.. And the article was included in Chemistry – A European Journal in 2011.Product Details of 177-10-6 This article mentions the following:

A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of enolsilanes, e.g. I (R = Bn, t-Bu, Boc-N), of high isomeric purity, saturated aldehydes or ketones, e.g. 2-methyl-3-phenylpropanal and 2-nonanone, or the corresponding saturated acetals, e.g. II, from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alc. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Product Details of 177-10-6).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 177-10-6

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Majumdar, Swapan et al. published their research in RSC Advances in 2014 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Formula: C8H14O2

Activation Of 1,3-Dioxolane By A Protic Ionic Liquid In Aqueous Media: A Green Strategy For The Selective Hydrolytic Cleavage Of Acetals and Ketals was written by Majumdar, Swapan;Chakraborty, Mithun;Maiti, Dilip K.;Chowdhury, Sandip;Hossain, Jewel. And the article was included in RSC Advances in 2014.Formula: C8H14O2 This article mentions the following:

A convenient method for the deprotection of acetals and ketals was achieved using an imidazolium based protic ionic liquid as a catalyst in aqueous medium via the dual activation of dioxolane. The protocol is highly efficient towards the deprotection of acyclic and cyclic acetals, ketals, benzylidene acetals and tetrahydropyranyl (THP) ethers, giving excellent yields. Functional groups such as tert-Bu ester, tert-Bu di-Me silyl (TBDMS), N-tert-butyloxycarbonyl (N-Boc), and double bond, mesyl, nitro, and glycosidic linkage were tolerated under the benign reaction conditions. Selective deprotection of the 5,6-isopropylidene moiety in 1,2:5,6-di-O-isopropylidene hexose and 3,5-cyclohexylidene moiety in pentose derivatives proceeded smoothly without affecting the 1,2-protected group. The attractive features of this new protocol are the use of mild reaction conditions, tolerance of a wide range of functional groups, use of relatively non-toxic solvent systems and recyclability of the ionic liquid catalyst. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Formula: C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Formula: C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Zhang, Ai-Hua et al. published their research in Guangpu Shiyanshi in 2009 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Synthetic Route of C8H14O2

The microwave synthesis of cyclohexanone glycol ketal catalyzed by activated carbon supported p-toluene sulfonic acid was written by Zhang, Ai-Hua;Yin, Du-Lin;Liu, Wen-Ping;Peng, Zhi-Yuan. And the article was included in Guangpu Shiyanshi in 2009.Synthetic Route of C8H14O2 This article mentions the following:

Cyclohexanone glycol ketal was synthesized from cyclohexanone and glycol using activated carbon supported p-toluene sulfonic acid as heterogeneous catalyst without solvent under microwave irradiation The effects of different factors such as mole ratio of reactants, catalyst dosage, microwave irradiation power, microwave irradiation time on the yield of cyclohexanone glycol ketal were carefully investigated. The activated carbon supported p-toluene sulfonic acid exhibited excellently catalytic activity. The best reaction conditions were as follows: the amount of cyclohexanone 0.2 mol, n(cyclohexanone):n(glycol)=1:1.6, the dosage of catalyst was 0.75% of the total mass of the reactants, microwave irradiation power 450W and radiation time 4min. Under this condition, the yield of cyclohexanone glycol ketal was up to 76.7%. The catalyst can be repeatedly used for six times without losing its catalytic activity. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Synthetic Route of C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Synthetic Route of C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Alikarami, Mohammad et al. published their research in Organic Chemistry: An Indian Journal in 2013 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, acetals and ketals with N,N’-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane peroxodisulfate under non-aqueous conditions was written by Alikarami, Mohammad;Abbasi, Zahra. And the article was included in Organic Chemistry: An Indian Journal in 2013.Computed Properties of C8H14O2 This article mentions the following:

An efficient and convenient conversion of trimethylsilyl and tetrahydropyranyl ethers, acetals and ketals to the corresponding carbonyl compounds with N,N’-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane peroxodisulfate under non-aqueous conditions is described. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Computed Properties of C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Maruyama, Kazuya et al. published their research in Macromolecules (Washington, DC, United States) in 2022 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C8H14O2

Alternating Cationic Copolymerization of Vinyl Ethers and Aryl-Substituted Cyclic Acetals: Structural Investigation of Effects of Cyclic Acetals on Copolymerizability was written by Maruyama, Kazuya;Kanazawa, Arihiro;Aoshima, Sadahito. And the article was included in Macromolecules (Washington, DC, United States) in 2022.COA of Formula: C8H14O2 This article mentions the following:

The effects of the structural difference of cyclic acetals were investigated in the cationic copolymerization with vinyl monomers via the concurrent vinyl-addition and ring-opening mechanisms. A series of alkyl- and aryl-substituted cyclic acetals were successfully copolymerized with 2-chloroethyl vinyl ether (CEVE) under appropriate conditions. In particular, copolymerization of an aryl-substituted 2-(4-methoxyphenyl)-1,3-dioxolane (PMPDOL) with CEVE involved exclusive crossover reactions between PMPDOL and CEVE, resulting in alternating copolymers. Copolymerization of PMPDOL and other vinyl ethers and styrene derivatives also proceeded via the frequent crossover reactions, while the copolymerization of 2-methyl-1,3-dioxolane, a methyl-substituted counterpart of PMPDOL, with vinyl monomers except for CEVE proceeded negligibly. The difference in the substituents of cyclic acetals significantly affected the electronic and steric environments around the carbocation generated in the propagation reaction, which is related to the frequency of the crossover reaction. Acid hydrolysis of alternating copolymers resulted in complete degradation and selective generation of a single compound due to the periodic incorporation of acetal structures in the main chains, which supported the well-defined structure of copolymers. The monomer reactivity ratios were also consistent with the copolymerizability difference between the aryl- and alkyl-substituted cyclic acetals. The structure-polymerizability relationship of cyclic acetals in the copolymerization was discussed based on the reaction mechanism during the propagating reaction. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6COA of Formula: C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Fang, Lin et al. published their research in Cuihua Xuebao in 2013 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

Carbon-coated mesoporous silica functionalized with sulfonic acid groups and its application to acetalization was written by Fang, Lin;Zhang, Kun;Chen, Lu;Wu, Peng. And the article was included in Cuihua Xuebao in 2013.Computed Properties of C8H14O2 This article mentions the following:

The inner surface of mesoporous silica SBA-15 was coated by a homogeneous polycyclic carbon layer through controlled carbonization of furfuryl alc. The composite was subsequently functionalized with sulfonic acid (-SO3H) groups to form a strong solid acid material, with a tunable acid site d. in the range of 0.38-0.84 mmol/g by varying the thickness of the carbon layer. Structural anal. and reaction data revealed that the solid acid catalyst exhibited high reactivity towards the acetalization of aldehydes or ketones with alcs. because of the uniform carbon coating of the mesopores, high acid site d., and its mech. stability. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Computed Properties of C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem