Applications of phase transfer catalysis. II. Synthesis of 2-(dihalomethyl)-1,3-dioxolanes and 2-(dihalomethyl)-1,3-dioxanes was written by Steinbeck, Karl. And the article was included in Chemische Berichte in 1979.Computed Properties of C4H7ClO2 This article mentions the following:
(Halomethyl)dioxolanes I (n = 1, R = H, optionally substituted alkyl, Ph, R1 = Cl) (34 compounds), I (n = 1, R = H, Me, Pr, CHMe2, Bu, hexyl, Ph, 4-MeOC6H4, R1 = Br) and dioxanes I (n = 2, R = H, Me, Pr, CHMe2, Bu, hexyl, Ph, 4-MeOC6H4, R1 = Cl) were prepared by C-H insertion reactions of dihalocarbenes generated by phase transfer catalysis; I were free of isomeric by-products. Electron-attracting substituents (R) decreased the yield in the reaction. The reactivity of the dioxanes was much lower than that of the dioxolanes. In the experiment, the researchers used many compounds, for example, 2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1Computed Properties of C4H7ClO2).
2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C4H7ClO2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem