Ma, Hong-Xin published the artcileControllable assembly, characterization and catalytic properties of a new Strandberg-type organophosphotungstate, SDS of cas: 177-10-6, the publication is Dalton Transactions (2016), 45(4), 1631-1637, database is CAplus and MEDLINE.
Using phenylphosphonic acid, simple tungstate and Cu(II) compounds as starting materials, an organic-inorganic hybrid Strandberg-type organophosphotungstate, {[(Cu(H2O)(μ-bipy))2(C6H5PO3)2W5O15]}n (bipy = 4,4′-bipyridyl) (1), was assembled successfully under hydrothermal conditions and characterized by physicochem. and spectroscopic methods. Compound 1 represents the 1st example of a transition metal complex modified organophosphotungstate cluster. In the crystal structure of 1, the polymeric 1-dimensional {Cu-bipy}n chains are interconnected by [(C6H5PO3)2W5O15]4- (abbreviated as {(C6H5P)2W5}) units into a 3-dimensional framework. A hollow Keggin isopolytungstate [H2W12O40]6- ({W12})-Cu(II) coordination polymer, {[Cu(bipy)2((μ-bipy)Cu(bipy))2(H2W12O40)]·12H2O}n (2), was obtained at different molar ratios of the starting materials and pH. The two Cu(II) coordination polymers exhibit good acid-catalytic activity for the synthesis of cyclohexanone ethylene ketal. Their fluorescence properties were studied.
Dalton Transactions published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, SDS of cas: 177-10-6.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem