Application In Synthesis of 2-Bromomethyl-1,3-dioxolane. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2-Bromomethyl-1,3-dioxolane, is researched, Molecular C4H7BrO2, CAS is 4360-63-8, about Electrochemical Umpolung C-H Functionalization of Oxindoles. Author is Pastor, Miryam; Vayer, Marie; Weinstabl, Harald; Maulide, Nuno.
Herein, a general electrochem. method to access unsym. 3,3-disubstituted oxindoles I (R1 = Me, Ph, Bn, cyclopentyl, etc.; R2 = Me, phenylethyl, Bn, etc.) by direct C-H functionalization where the oxindole fragment behaves as an electrophile was reported. This Umpolung approach does not rely on stoichiometric oxidants and proceeds under mild, environmentally benign conditions. Importantly, it enables the functionalization of these scaffolds through C-O, and by extension to C-C or even C-N bond formation.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem