Fasi, A. published the artcileRing opening reactions of methyloxirane over DZSM-5 and DAlMCM-41 molecular sieves – a mechanistic study, Product Details of C6H12O2, the publication is Studies in Surface Science and Catalysis (2001), 3678-3685, database is CAplus.
The ring opening reactions of methyloxirane on DZSM-5 and DAlMCM-41 aluminosilicates were studied in a pulse microreactor at 363 K. Deuterium distribution in the products was monitored Single C-O scission as well as dimerization occurred on both mol. sieves. In these reactions Bronsted and Lewis sites were involved Deuterium distribution revealed details of transformation pathways. It was found the main reaction channel, where deuterium exchange does not occur, involves exclusively the Lewis sites at the potential exchange sites. For deuterium exchange to occur during ring opening at least one Bronsted site is necessary. For dimerization when deuterium exchange takes place many active site combinations may be envisaged, however, for the formation of the dioxolane derivatives two neighboring Bronsted-Lewis site pairs, while for the formation of dioxane derivatives the interplay of one Bronsted-Lewis acid pair and a Lewis-Lewis acid pair seem to be the most advantageous.
Studies in Surface Science and Catalysis published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Product Details of C6H12O2.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem