Stereoselective Hydrosilylation of Enals and Enones Catalysed by Palladium Nanoparticles was written by Benohoud, Meryem;Tuokko, Sakari;Pihko, Petri M.. And the article was included in Chemistry – A European Journal in 2011.Product Details of 177-10-6 This article mentions the following:
A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of enolsilanes, e.g. I (R = Bn, t-Bu, Boc-N), of high isomeric purity, saturated aldehydes or ketones, e.g. 2-methyl-3-phenylpropanal and 2-nonanone, or the corresponding saturated acetals, e.g. II, from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alc. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Product Details of 177-10-6).
1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 177-10-6
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem