Highly efficient acetalization and ketalization catalyzed by cobaloxime under solvent-free condition was written by Zong, Yang;Yang, Liting;Tang, Shanyu;Li, Longjia;Wang, Wanjie;Yuan, Bingxin;Yang, Guanyu. And the article was included in Catalysts in 2018.Related Products of 6413-10-1 The following contents are mentioned in the article:
An efficient catalytic system was developed for the acetalization and ketalization of carbonyl compounds with polyhydric alcs. under mild solvent-free conditions. In the presence of 0.1 mol% CoCl2 and 0.2 mol% dimethylglyoxime at 70° under 5 KPa pressure for 1 h, 95.3% conversion of cyclohexanone and 100% selectivity of the corresponding cyclic ketal could be obtained, where TOF reached as high as 953 h-1. It is proposed that the in situ generated planar tetracoordinate cobaloxime played the key role in the catalytic cycle and was responsible for the excellent catalytic performance. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Related Products of 6413-10-1).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Related Products of 6413-10-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem