Anion-induced 3d-4f luminescent coordination clusters: structural characteristics and chemical fixation of CO2 under mild conditions was written by Zhang, Ruilian;Wang, Li;Xu, Cong;Yang, Huan;Chen, Wanmin;Gao, Guoshu;Liu, Weisheng. And the article was included in Dalton Transactions in 2018.Formula: C8H10O5 This article mentions the following:
Two series of anion-induced 3d-4f luminescent clusters Ln2Zn2L4(NO3)4(μ3-OH)2·CH3CN (HL = Me 3-methoxysalicylate; LnIII = Eu3+, Tb3+, Er3+, Yb3+, Nd3+) and Ln2Zn4(μ3-OH)2L4(OAc)8·CH3CN (LnIII = Tb3+, Nd3+) based on μ3-OH group were synthesized and characterized. The difference in anions not only leads to significant structural changes, but also changes the luminescent properties of the 3d-4f coordination clusters. These complexes show excellent catalytic performance for CO2 conversion to obtain cyclic carbonates with wide substrate scopes and high selectivity under mild conditions. Turnover numbers were up to 9000, and turnover frequencies obtained were 660 h-1. The ligand is simple and the complexes are easily obtained even on a large scale. Also, these complexes also feature lanthanide-characterized luminescence both in visible and near IR regions with relatively long luminescence lifetimes and high quantum yields, suggesting promising multifunctional applications. In the experiment, the researchers used many compounds, for example, (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5Formula: C8H10O5).
(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Formula: C8H10O5
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem