Arene-catalyzed lithiation reactions with lithium at low temperature was written by Yus, Miguel;Ramon, Diego J.. And the article was included in Journal of the Chemical Society, Chemical Communications in 1991.Name: 2-(4-Chlorobutyl)-1,3-dioxolane This article mentions the following:
The reaction of functionalized alkyl chlorides or Ph sulfides with an excess of lithium powder in the presence of a catalytic amount of an arene (1%; naphthalene, biphenyl, 4,4′-di-tert-butylbiphenyl) in THF at -78° gives the corresponding organolithium compounds, which react with electrophiles such as water, isobutyraldehyde, or cyclohexanone to yield the expected reaction products. In the experiment, the researchers used many compounds, for example, 2-(4-Chlorobutyl)-1,3-dioxolane (cas: 118336-86-0Name: 2-(4-Chlorobutyl)-1,3-dioxolane).
2-(4-Chlorobutyl)-1,3-dioxolane (cas: 118336-86-0) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Name: 2-(4-Chlorobutyl)-1,3-dioxolane
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem