Yasnitskii, B. G. et al. published their research in Zhurnal Obshchei Khimii in 1964 | CAS: 2568-30-1

2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C4H7ClO2

Derivatives of cyclic acetals. I. Cyclic chloro acetals and their derivatives was written by Yasnitskii, B. G.;Sarkisyants, S. A.;Ivanyuk, E. G.. And the article was included in Zhurnal Obshchei Khimii in 1964.COA of Formula: C4H7ClO2 This article mentions the following:

The sulfonated polystyrene ion-exchange resin (KU-1) was found to be an effective agent for formation of cyclic acetals of ClCH2CHO. Thus, heating 1 kg. 98% glycerol with 475 g. (ClCH2CHO)2.H2O and 28 g. KU-1 resin 10-12 h. at 80-90° gave 96% glycerol α,β-chloroacetal, b9 125-30°. Similarly were prepared 60-86% cyclic acetals of ClCH2CHO and ethylene glycol (I), propylene glycol, α-chloroglycerol (II), diethylene glycol, pentaerythritol, mannitol, and sorbitol. The cyclic acetal (IIa) of ClCH2CHO and I added slowly to tert-BuOK in tert-BuOH and then heated 2 h. at 80-5° gave 85% III, b9 56-7°, d20 1.0096, n20D 1.4350. Similarly were prepared 52% IV, b. 127-8°, -, 1.4465 (at 25°); 75.2% V, b. 169-70°, 1.2346, 1.4530; and 40% VI, m. 52°. To 25 g. K in 500 g. BuOH was added 78.3 g. IIa (b9 52-3°, 1.2475, 1.4474) and the mixture kept 10-12 h. at 110-20° to give 62.5% VII, b5 47-9°, 0.9892, 1.4225, also formed from III and KOH in BuOH. Similarly was prepared 85% the ethoxy analog. The acetals based on ketene readily formed glassy polymers. The following constants were given for the cyclic chloroacetals (alc., b.p., d20, and n20D given): glycerol, b0 125-30°, 1.3245, 1.475; propylene glycol, b5 45-6°, 1.1597, 1.4420; α-chloroglycerol, b4 82-3°, 1.3498, 1.4750; diethylene glycol, b5 115-18° (m. 45-6°), 1.1670, 1.4562; pentaerythritol, – (m. 92°), -, -; mannitol, b·1-0.2 195-200°, 1.4473, 1.5048; sorbitol, b0.05 219-20°, 1.4484, 1.5096. In the experiment, the researchers used many compounds, for example, 2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1COA of Formula: C4H7ClO2).

2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C4H7ClO2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem