Yang, Zhi-Wang published the artcileBaeyer-Villiger oxidation and acetalization of cyclic ketones on SO2-4/SnO2-Fe2O3 solid acid catalysts, Formula: C8H14O2, the publication is Wuli Huaxue Xuebao (2012), 28(9), 2148-2154, database is CAplus.
Fe-doped SO2-4/SnO2 (STF) solid acid catalysts with different amounts of iron were prepared via co-condensation, followed by sulfation and calcination. These materials were characterized by Fourier transform IR (FTIR) spectroscopy, x-ray powder diffraction (XRD), N2 adsorption-desorption anal. (BET), thermogravimetric (TG) anal., and SEM. The Fe-doped catalysts exhibited more activity than undoped catalysts in acetalization reactions of 4-tert-butylcyclohexanone and diols. The catalytic acetalization of several ketones and 1,2-diols with the SO2-4/SnO2-Fe2O3 catalysts (with the Fe/Sn molar ratio of 0.5) were studied. The influence of the reaction time and the amount of the catalysts on the acetalization were also investigated. In addition, the high performance of this Fe-modified catalyst was demonstrated in the Baeyer-Villiger oxidation of cyclic ketones. The catalyst can be recycled several times without any significant loss in catalytic activity.
Wuli Huaxue Xuebao published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C12H23N3S, Formula: C8H14O2.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem