Qiao, Jianhui; Chang, Wenju; Zhao, Wenxuan; Liang, Yong; Wang, Shaozhong published an article about the compound: 5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine( cas:1265884-98-7,SMILESS:N1(P2OC3=CC=C4C=CC=CC4=C3C5=C6C=CC=CC6=CC=C5O2)C7=CC=CC=C7C=CC8=CC=CC=C81 ).Application In Synthesis of 5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1265884-98-7) through the article.
Kinetic resolution of racemic spiroindolines I [R = H, Me, MeO, F, Cl; X = H, Me, Cl; Y = H, Me, MeO, F, Cl; Z = H, Me, MeO, F; no stereo] with s factors of ≤15200 was developed to access enantiomerically enriched indole-annulated medium-sized lactams II [R1 = Ph, 2-thienyl, 2-naphthyl, etc.] and spiroindolines I [stereo = R] through Ir-catalyzed asym. allylative ring-opening reaction. D. functional theory calculations supported the idea that the accurate discrimination of two spiroindoline enantiomers by (η3-allyl)-iridium(III) species and the perfect central-to-axial chirality conversion during C-C bond fragmentation ensure the stereoselective formation of two contiguous stereogenic centers and one axis in the medium-sized lactams.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem