Wang, Jian-Ping published the artcileTwo Strandberg-type organophosphomolybdates: synthesis, crystal structures and catalytic properties, Related Products of dioxole, the publication is Dalton Transactions (2014), 43(45), 17172-17176, database is CAplus and MEDLINE.
Two novel Strandberg-type organophosphomolybdate hybrid compounds [(Cu(H2O))2(μ-bipy)2(C6H5PO3)2Mo5O15]n (1) and [(Cu(H2O)2)2(μ-bipy)(C6H5PO3)2Mo5O15]n (2) (bipy = 4,4′-bipyridyl) were prepared under mild hydrothermal conditions and structurally characterized by physicochem. and spectroscopic methods. Single crystal x-ray diffraction anal. reveals that compounds 1 and 2 are polyoxometalate-based Cu-coordination polymers with a three-dimensional framework. In 1, the Cu2+ ions not only link [(C6H5PO3)2Mo5O15]4- (abbreviated as {(C6H5P)2Mo5}) polyanions, but also act as connectors of bipy ligands to produce two sym. 1-dimensional chains, and all 1-dimensional chains are further held together by polyanions to generate a 3-dimensional network. In 2, each {(C6H5P)2Mo5} polyanion acting as a hexadentate ligand links four Cu(II)-bipy/H2O units, forming 2-dimensional plane structures, which are further bridged by Cu(II)-bipy-Cu(II) fragments to generate a 3-dimensional network. Their fluorescence properties and catalytic properties for the synthesis of cyclohexanone ethylene ketal were also studied.
Dalton Transactions published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C19H14N2, Related Products of dioxole.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem