New discoveries in chemical research and development in 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 3458-28-4, Name is (2S,3S,4R,5R)-2,3,4,5,6-Pentahydroxyhexanal, molecular formula is C6H12O6. In an article, author is Zdvizhkov, Alexander T.,once mentioned of 3458-28-4, Safety of (2S,3S,4R,5R)-2,3,4,5,6-Pentahydroxyhexanal.
Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones
Treatment of 1-aryl-2-allylalkane-1,3-diones with I-2/H2O2 system in the presence of catalytic amount of phosphomolybdic acid affords furo[2,3-c][1,2]dioxole derivatives. With other acidic catalysts such as BF3 center dot Et2O, SnCl4, H2SO4 or TsOH, mixtures with linear 4-acyloxy-2,5-diiodoalkan-1-ones are formed.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem