Synthetic Route of C34H22NO2P. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine, is researched, Molecular C34H22NO2P, CAS is 1265884-98-7, about Total Synthesis of (+)-Asperolide C by Iridium-Catalyzed Enantioselective Polyene Cyclization. Author is Jeker, Oliver F.; Kravina, Alberto G.; Carreira, Erick M..
The first total synthesis of tetranorlabdane diterpenoid asperolide C (I) is reported. This study demonstrates the use of an enantioselective polyene cyclization for natural product synthesis and relies on modern iridium catalysis to prepare the carbobicyclic core scaffold. The synthesis also features cross-coupling reactions, specifically, the Pd-mediated coupling of a dienol triflate, H2C:CHC(OTf):CHCH2CH2OCH2C6H4OMe-4, with Me3SiCH2B(OH)2, which produces an allylic silane.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem