New Advances in Chemical Research, April 2021. Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. 91526-18-0, Name is 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one, SMILES is CC1=C(CO)OC(=O)O1, belongs to dioxole compound. In a document, author is Butkus, E, introduce the new discover, Name: 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one.
Chromatographic enantiomer separation and absolute configuration of spiro[benzo-1,3-dioxole-2,9 ‘-bicyclo[3.3.1]nonan]-2 ‘-one and the corresponding diastereomeric hydroxy acetals
The enantiomers of spiro[benzo-1,3-dioxole-2,9′-bicyclo[3.3.1]nonan]-2′-one 2 and the corresponding diastereomeric exo-2′- and endo-2’-hydroxy acetals 3a,b obtained from this monoacetal were solved by HPLC on a swollen microcrystalline triacetylcellulose column. The absolute configuration of the enantiomers of 2 and 3a,b was assigned based on the signs of the Cotton effect and employing the octant rules for the carbonyl and the aromatic chromophores The low intensity of the band at 290 nm in the CD spectrum of monoacetal 2 was accounted far by the interaction of the carbonyl and aromatic chromophores.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 91526-18-0, in my other articles. Name: 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one.
Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem