A practical RuCl3-catalyzed oxidation using trichloroisocyanuric acid as a stoichiometric oxidant under mild nonacidic conditions was written by Yamaoka, Hidenori;Moriya, Narimasa;Ikunaka, Masaya. And the article was included in Organic Process Research & Development in 2004.Electric Literature of C12H20O6 This article mentions the following:
The combined use of catalytic RuCl3 and stoichiometric trichloroisocyanuric acid in the presence of n-Bu4NBr and K2CO3 allowed smooth oxidation of primary alcs. to carboxylic acids. Secondary alcs. can be oxidized to ketones when using the same set of the reagents. By proceeding under the nonacidic biphasic conditions dispensing with hazardous reagents, the oxidation reactions were applicable to structurally diverse alcs., easy to work up, environmentally benign, and basically high-yielding. In the experiment, the researchers used many compounds, for example, (3aS,4S,6R,6aS)-6-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol (cas: 14131-84-1Electric Literature of C12H20O6).
(3aS,4S,6R,6aS)-6-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol (cas: 14131-84-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Electric Literature of C12H20O6
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem