Recommanded Product: 305798-02-1. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2-Bromo-6-(bromomethyl)naphthalene, is researched, Molecular C11H8Br2, CAS is 305798-02-1, about Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines. Author is Ye, Wenchao; Zhang, Laijun; Ni, Chuanfa; Rong, Jian; Hu, Jinbo.
An unprecedented [3+2] cycloaddition between N-tert-butanesulfinyl imines and arynes provides a stereoselective method for the synthesis of cyclic sulfoximines. Not only does the difluoro(phenylsulfonyl)methyl group play an important role in facilitating the cycloaddition reaction, it can also be removed or substituted through the transformation of the difluorinated cyclic sulfoximines, e.g. I, to cyclic sulfinamides, e.g. II.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem