Schurig, V. published the artcileEnantiomer analysis by complexation gas chromatography. Scope, merits and limitations, COA of Formula: C6H12O2, the publication is Journal of Chromatography (1988), 441(1), 135-53, database is CAplus.
The application of complexation gas chromatog. in comtemporary enantiomer anal. was investigated. Enantiomers were separated without derivatization on Chiral metal stationary phases, such as manganese(II), cobalt(II), and nickel(II) bis[3-(heptafluorobutanoyl)-(1R)-camphorate], coated on high-resolution glass and fused-silica open-tubular columns. Enantiomeric excesses (ee) up to 99.9% can be precisely determined by complexation gas chromatog. Employing the gas chromatog.-mass spectrometry (single ion monitoring) technique, the determination of ee and absolute configurations of solutes, present in complex mixtures, can be performed at the low picogram level. For the first time, pertinent sources of error in the gas chromatog. determination of ee were identified and novel exptl. verifications thereof are presented. Interconversion profiles due to inversion of configuration during enantiomer separation by complexation gas chromatog. have been detected. Inconsistencies of an empirical quadrant rule, correlating absolute configuration and order of elution of cyclic ethers from nickel(II) bis[3-(heptafluorobutanoyl)-(1R)-camphorate], are reported.
Journal of Chromatography published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C8H7NO4, COA of Formula: C6H12O2.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem