Schnurpfeil, D.’s team published research in Journal fuer Praktische Chemie/Chemiker-Zeitung in 336 | CAS: 1193-11-9

Journal fuer Praktische Chemie/Chemiker-Zeitung published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Quality Control of 1193-11-9.

Schnurpfeil, D. published the artcileLiquid-phase oxidation of 1,3-dioxolanes, Quality Control of 1193-11-9, the publication is Journal fuer Praktische Chemie/Chemiker-Zeitung (1994), 336(2), 155-9, database is CAplus.

The oxidation rate and the kind of oxidation products in the oxidation reactions of the 1,3-dioxolanes with mol. oxygen in liquid phase were investigated. The 2-methyl-substituted 1,3-dioxolane has a lower, the 4-methyl-substituted 1,3-dioxolane has a higher oxidation rate than the non-substituted 1,3-dioxolane. The 2,2-disubstituted 1,3-dioxolanes show no oxidation but a hydrolytic reaction. The main-products of the liquid-phase oxidation of the 1,3-dioxolanes are the glycolcarbonic acid monoesters and the 2-oxo-1,3-dioxolanes. Their formation is proved by gas chromatog., GC/MS-coupling, DC and 13C-NMR-spectroscopy.

Journal fuer Praktische Chemie/Chemiker-Zeitung published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Quality Control of 1193-11-9.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem