Salomaa, Pentti published the artcileThe kinetics of the uncatalyzed and acid-catalyzed hydrolysis of 1,3-dioxol-4-one and its derivatives. III. Experiments in moderately concentrated acids and in deuterated solvents, Application of 2,2,4-Trimethyl-1,3-dioxolane, the publication is Acta Chemica Scandinavica (1966), 20(5), 1263-72, database is CAplus.
cf. CA 63, 12995c. The rates of hydrolysis of 1,3-dioxolones (I) containing 0, 1, or 2 Me substituents on the C atom between the 2 ether O atoms, in moderately concentrated HCl and in mixtures of light and heavy water, indicate that the I which have no substituents on the C-2 hydrolyze by the normal type of acid-catalyzed ester hydrolysis. The 2-Me-substituted I are not hydrolyzed by either a normal type or an A-1 type ester hydrolysis. It is suggested that a H2O mol. is involved in the formation of the critical complex. This idea is supported by experiments in light and heavy water and in their mixtures The gross D solvent-isotope effect (kD/kH = 1.68) is comparable to that found in the normal type of ester hydrolysis, being lower than in A-1 reactions of acetals and acetal-esters. The behavior in H2O-D2O mixtures of different compositions conforms to an equation which is based on 3 exchangeable H atoms in the critical complex. A discussion of the hydrolysis mechanism of 2-Me-substituted I is presented.
Acta Chemica Scandinavica published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Application of 2,2,4-Trimethyl-1,3-dioxolane.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem