Ren, Li-guo et al. published their research in Shiyou Huagong Gaodeng Xuexiao Xuebao in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.COA of Formula: C8H14O4

Phosphate-modified TiO2 solid acid catalysts was written by Ren, Li-guo;Gao, Wen-yi;Zhang, Xiao-li. And the article was included in Shiyou Huagong Gaodeng Xuexiao Xuebao in 2006.COA of Formula: C8H14O4 The following contents are mentioned in the article:

A phosphate-modified TiO2 solid acid catalyst was prepared from TiCl4 and H3PO4 by precipitation, aging, filtration, washing, drying, impregnation and calcination processes. The acidic property of catalyst was determined by Hammett indicator method and n-butylamine titration as well as pyridine adsorption FT-IR spectrometry. The characterization of the catalyst was performed using XRD, FT-IR, TG-DTA, and N2 adsorption methods. The effect of mass fraction of phosphate and calcination temperature on the acidic property, textural property and catalytic performance of phosphate-modified TiO2 solid acid catalysts was studied. TG-DTA curves and XRD patterns showed that phosphate could stabilize the anatase phase and prevent grains from growing. FT-IR spectra showed that phosphate is strongly bound to the TiO2 surface in a bidentate fashion. N2 adsorption and n-butylamine titration showed that surface area and pore volume as well as total acidity increased with the increase of mass fraction of phosphate when it was less than 7.5% and thereafter decreased. Hammett indicator method and pyridine adsorption FT-IR spectra showed that solid superacid was formed at 425-575°, and there were Lewis and Bronsted acidic centers on surface. The phosphate-modified TiO2 solid acid catalyst had good catalytic performance in the ketalization of Et acetoacetate and 1,2-ethylene glycol. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1COA of Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.COA of Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem