Preparation and application of magnetic solid acid SO42--/ZrO2/Fe3O4/WO3 for synthesis of fructone was written by Ren, Bo;Fan, Meiqing;Wang, Jun;Jing, Xiaoyan. And the article was included in Solid State Sciences in 2011.Synthetic Route of C8H14O4 The following contents are mentioned in the article:
A synthesis route to SO42--/ZrO2/Fe3O4/WO3 solid acid catalysts with magnetism is reported through chem. co-precipitation method. The obtained solid acid catalysts are characterized in detail by x-ray diffraction, Different Scanning Calorimetry (DSC), TEM, Vibrating Sample Magnetometer (VSM), N2 adsorption-desorption, Temperature-Programmed Pesorption (TPD) of ammonia. The introduction of WO3 and Fe3O4 strongly inhibit the phase transformation of zirconia and improve the thermal stability of zirconia. Furthermore, the obtained materials present super-paramagnetism and magnetism. The super acid exhibits high catalytic activity in forming fructone by condensation. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Synthetic Route of C8H14O4).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Synthetic Route of C8H14O4
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem