Preparation of fructone using copper methanesulfonate as catalyst was written by Peng, Anshun;Chen, Changxing. And the article was included in Riyong Huaxue Gongye in 2005.Category: dioxole The following contents are mentioned in the article:
Fructone (i.e., 2-methyl-1,3-dioxolane-2-acetic acid Et ester) was synthesized using Et acetoacetate and glycol as starting materials and copper methanesulfonate as catalyst. Factors influencing the yield were examined by the orthogonal experiments The optimum conditions were as follows: n(Et acetoacetate)/n(glycol) 1:1.5, catalyst dosage 7.5 g, water carrying agent 7.5 mL, reaction under reflux condition for 3 h. The yield can achieve 88.2%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Category: dioxole).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Category: dioxole
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem