Chemical Absorption of Carbon Dioxide into Glycidyl Methacrylate Solution with Tetrabutylammonium Bromide was written by Park, Sang-Wook;Choi, Byoung-Sik;Lee, Byung-Don;Park, Dae-Won;Kim, Seong-Soo. And the article was included in Separation Science and Technology in 2006.HPLC of Formula: 13818-44-5 This article mentions the following:
The reaction for fixation of carbon dioxide was carried out in a semi-batch stirred tank of glycidyl methacrylate solution with tetrabutylammonium bromide as catalyst at 101.3 kPa. The measured rate of uptake of carbon dioxide was used to obtain the kinetic parameters for the reaction steps to form five membered cyclic carbonates, i.e., reversible reaction of glycidyl methacrylate with tetrabutylammonium bromide to form an intermediate and an irreversible reaction between carbon dioxide and the intermediate to form the cyclic carbonate. An empirical correlation formula between the reaction rate constants and the solubility parameters of the solvents, such as toluene, N-methyl-2-pyrrolidinone, and DMSO, is presented. In the experiment, the researchers used many compounds, for example, (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5HPLC of Formula: 13818-44-5).
(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 13818-44-5
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem