Facile synthesis of enol ethers by cleavage of α-bromoacetals and α-bromoketals mediated by SmI2 was written by Park, H. S.;Kim, S. H.;Park, M. Y.;Kim, Y. H.. And the article was included in Tetrahedron Letters in 2001.Synthetic Route of C10H11BrO2 This article mentions the following:
Cyclic α-bromo acetals, cyclic α-bromo ketals and cyclic α-bromo thioketals, derived from cyclic and acyclic ketones and aldehydes, reacted with samarium diiodide at -78° in THF to furnish enol ethers or thioenol ethers containing hydroxy or thiol moieties in high yields. In the experiment, the researchers used many compounds, for example, 2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1Synthetic Route of C10H11BrO2).
2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Synthetic Route of C10H11BrO2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem