Catalytic conversion of carbon dioxide using phase transfer catalysts was written by Park, D. W.;Moon, J. Y.;Yang, J. G.;Lee, J. K.. And the article was included in Energy Conversion and Management in 1997.Application In Synthesis of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate This article mentions the following:
Syntheses of 5-membered cyclic carbonates from CO2 and glycidyl methacrylate or diglycidyl 1,2-cyclohexanedicarboxylate were investigated in view of the characteristics of phase-transfer catalysts, reaction mechanisms, and kinetics. Quaternary salts showed good conversion of epoxide at 1 atm of CO2 pressure. Among the salts tested, those having a larger alkyl group and a more nucleophilic counter-anion exhibited better catalytic activity. Kinetic studies in a semi-batch reactor, through which a slow stream of CO2 was continuously passed, showed that the reaction rate was pseudo-first order with respect to epoxide. In a batch autoclave reactor with high CO2 pressure, however, the reaction rate showed second order kinetics. The reaction was also carried out with an insoluble phase-transfer catalyst, quaternary ammonium chloride anchored to metal oxide, to facilitate the recovery of catalyst. In the experiment, the researchers used many compounds, for example, (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5Application In Synthesis of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate).
(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Application In Synthesis of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem