Yang, Liu’s team published research in Yingyong Huaxue in 31 | CAS: 177-10-6

Yingyong Huaxue published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C10H6Br2, Formula: C8H14O2.

Yang, Liu published the artcileSynthesis of cyclohexanone ethylene ketal catalyzed by Keggin type biimidazole tungstogermanate, Formula: C8H14O2, the publication is Yingyong Huaxue (2014), 31(11), 1310-1316, database is CAplus.

A Keggin-type biimidazole tungstogermanate (H4biim) [H2GeW12O40]·18H2O (1b, H2biim = 2,2′-biimidazole), as a catalyst for the synthesis of cyclohexanone ethylene ketal, was designed and synthesized. It was characterized by single crystal X-ray diffraction anal., IR spectroscopy (FT-IR), UV spectroscopy (UV), thermogravimetry-DTA (TG-DTA) and X-ray powder diffraction (XRD). Factors, such as the molar ratio of cyclohexanone to ethylene glycol, catalyst loading and reaction time, on the yield were investigated. The exptl. results show that the product yield reaches 90% under the optimal conditions: n(cyclohexanone):n(1,2-ethanediol) = 1:1.4, n(1b, based on W): n(cyclohexanone) = 1:260, and reaction time 2 h. The catalyst can be reused and has good stability in the catalytic reaction.

Yingyong Huaxue published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C10H6Br2, Formula: C8H14O2.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Bonilla-Landa, Israel’s team published research in Current Organic Synthesis in 16 | CAS: 177-10-6

Current Organic Synthesis published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Category: dioxole.

Bonilla-Landa, Israel published the artcileHafnium(IV) Chloride Catalyzes Highly Efficient Acetalization of Carbonyl Compounds, Category: dioxole, the publication is Current Organic Synthesis (2019), 16(6), 913-920, database is CAplus and MEDLINE.

Hafnium(IV) tetrachloride efficiently catalyzes the protection of a variety of aldehydes and ketones RC(O)R1 (R = Ph, 4-butylphenyl, pyridin-2-yl, octyl, etc.; R1 = H, Me, Et), including benzophenone, acetophenone, and cyclohexanone, to the corresponding di-Me acetals and 1,3-dioxolanes, RC(OR2)2R1 (R2 = Me, -(CH2)2-) under microwave heating. Substrates possessing acid-labile protecting groups (TBDPS and Boc) chemoselectively generated the corresponding acetal/ketal in excellent yields.

Current Organic Synthesis published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Category: dioxole.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Yang, Hua’s team published research in Zeitschrift fuer Anorganische und Allgemeine Chemie in 640 | CAS: 177-10-6

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C3H12Cl2N2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Yang, Hua published the artcileSyntheses, Structures, and Catalytic Activities of Copper(I) Complexes with the Ligand 2-(4,5-Diphenyl-1H-imidazol-2-yl)pyridine, Recommanded Product: 1,4-Dioxaspiro[4.5]decane, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (2014), 640(2), 394-397, database is CAplus.

Two copper(I) complexes [Cu(HL)I]2·2EtOH (1) and [Cu(HL)3]I·MeOH (2) were synthesized via the reactions of HL [HL = 2-(4,5-diphenyl-1H-imidazol-2-yl)pyridine] and CuI in EtOH and MeOH, resp., under solvothermal conditions. The complexes were characterized by x-ray single crystal diffraction, IR spectroscopy, and elemental anal. Compounds 1 and 2 are catalytically active towards ketalization reaction, giving various ketals under mild conditions.

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C3H12Cl2N2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Xiang, Shiyin’s team published research in Jingxi Shiyou Huagong Jinzhan in 18 | CAS: 177-10-6

Jingxi Shiyou Huagong Jinzhan published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C13H18N2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Xiang, Shiyin published the artcileSynthesis of cyclohexanone ethylene ketal catalyzed by H6P2W9Mo9O62/SiO2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane, the publication is Jingxi Shiyou Huagong Jinzhan (2017), 18(6), 45-48, database is CAplus.

H6P2W9Mo9O62/SiO2 was synthesized in a sol-gel process, and the thermal stability, structure and morphol. of H6P2W9Mo9O62/SiO2 were analyzed with X-ray diffractometer (XRD), FTIR Raman spectrometer, differential thermal analyzer (TG) and scanning electron microscope (SEM). Cyclohexanone ethylene ketal was synthesized with cyclohexanone and ethylene glycol as the reaction materials and H6P2W9Mo9O62/SiO2 as the catalyst, and the effects of the molar ratio of alc. ketone, the catalyst amount, the reaction time, and the cyclohexane amount on the synthesis of ketal were studied. According to the results, the yield of cyclohexanone ethylene ketal can reach 80.4% at the following conditions, i.e. n (cyclohexanone) : n (ethylene glycol)=1:1.3, the catalyst amount accounts for 0.8% of total reactants, and the reaction time is 45 min.

Jingxi Shiyou Huagong Jinzhan published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C13H18N2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Krapcho, A. Paul et al. published their research in Science of Synthesis in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Product subclass 3: sodium halides and sodium cyanide was written by Krapcho, A. Paul. And the article was included in Science of Synthesis in 2006.Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

A review of the applications of sodium halides and sodium cyanide in organic synthesis. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Lopez, Alberto M. et al. published their research in Organic Letters in 2018 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.HPLC of Formula: 6413-10-1

Correction to “Tin-Free Access to the ABC Core of the Calyciphylline A Alkaloids and Unexpected Formation of a D-Ring-Contracted Tetracyclic Core” [Erratum to document cited in CA168:398126] was written by Lopez, Alberto M.;Ibrahim, Ahmad A.;Rosenhauer, Gregory J.;Sirinimal, Hansamali S.;Stockdill, Jennifer L.. And the article was included in Organic Letters in 2018.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

In the original publication, there are errors in scheme 6 and the first sentence of the paragraph that describes scheme 6; the correction is provided here. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.HPLC of Formula: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Zhang, Fujuan et al. published their research in Xuchang Xueyuan Xuebao in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 6413-10-1

Study on catalytic synthesis of fructone using nanosolid superacid SO42-/TiO2 was written by Zhang, Fujuan;Wang, Shuxia. And the article was included in Xuchang Xueyuan Xuebao in 2006.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

Fructone was prepared from Et acetoacetate and ethylene glycol using nanosolid superacid sulfated TiO2 as catalyst. Under optimum conditions, the product yield reached 93.2%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Varabyeva, Nastassia et al. published their research in Organic Letters in 2021 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Ti(OiPr)4-Enabled Dual Photoredox and Nickel-Catalyzed Arylation and Alkenylation of Cyclopropanols was written by Varabyeva, Nastassia;Barysevich, Maryia;Aniskevich, Yauhen;Hurski, Alaksiej. And the article was included in Organic Letters in 2021.Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

The Ti(OiPr)4 additive enables this elusive cross-coupling with aryl and alkenyl bromides e.g., 4-bromoanisole leading to β-substituted ketones e.g., 1-(4-methoxyphenyl)-5-phenylpentan-3-one. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Tan, Jason Samuel et al. published their research in Organic Letters in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Total Synthesis of Topopyrones B and D was written by Tan, Jason Samuel;Ciufolini, Marco A.. And the article was included in Organic Letters in 2006.Product Details of 6413-10-1 The following contents are mentioned in the article:

We describe a straightforward synthesis of topopyrones B and D (I, R = Cl, H, resp.), which are potent and selective inhibitors of topoisomerase I. The chem. should be suitable for addnl. structure-activity relationship (SAR) work. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Product Details of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Astashko, Dmitry A. et al. published their research in Tetrahedron Letters in 2011 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

A convenient route to 2,6-dialkyl-2,3-dihydro-4H-pyran-4-ones via oxidative cleavage of protected 1-(2-oxoalkyl)-cyclopropanols. Synthesis of (±)-hepialone and its natural congener was written by Astashko, Dmitry A.;Tyvorskii, Vladimir I.. And the article was included in Tetrahedron Letters in 2011.Product Details of 6413-10-1 The following contents are mentioned in the article:

An efficient strategy for the synthesis of 2,6-dialkyl-2,3-dihydro-4H-pyran-4-ones has been developed, the key steps of which are oxidative cleavage of the three-membered rings of 1-(2-oxoalkyl)-cyclopropanols and acid-promoted cyclization of the resulting β-hydroxyketones. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Product Details of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem