On May 31, 2000, Nouguier, Robert published an article.Computed Properties of 38838-06-1 The title of the article was Synthesis of methyl esters of 6,7-dideoxy-α-D-manno (and gluco)octopyranosiduronic acids and of methyl 5,6-dideoxy-β-D-riboheptofuranosiduronic acids by one-pot two carbon extension steps. And the article contained the following:
In DMSO at 100 °C, the anion of di-Me malonate reacts with primary iodides derived from mannose, glucose and ribose. Without isolation of the di-Me sugar-malonyl derivative, addition in the same flask of NaCl and H2O and heating at 160 °C leads to the decarbomethoxylated product in good yield. This is a very simple one-pot method for 2-C extension of carbohydrates chains. The experimental process involved the reaction of (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole(cas: 38838-06-1).Computed Properties of 38838-06-1
The Article related to uronic acid ester synthesis malonate condensation homologation, Carbohydrates: Acids and other aspects.Computed Properties of 38838-06-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem