Enantioselective microbial hydrolysis of dissymmetrical cyclic carbonates with disubstitution was written by Nogawa, Masaki;Sugawara, Satomi;Iizuka, Rie;Shimojo, Megumi;Ohta, Hiromichi;Hatanaka, Minoru;Matsumoto, Kazutsugu. And the article was included in Tetrahedron in 2006.Product Details of 6413-10-1 The following contents are mentioned in the article:
Enantioselective microbial hydrolysis of C1 and C2 dissym. cyclic carbonates with disubstitution (Me and another groups) has been developed. Pseudomonas diminuta (FU0090), a bacterium, efficiently catalyzes the hydrolysis of five-membered cyclic carbonates. While the trans-substrates are hydrolyzed with low enantioselectivities and/or reactivities, the microbe hydrolyzes the cis-substrates with very high enantioselectivities to afford the corresponding almost optically pure anti-(2R,3S)-diols. On the other hand, six-membered trans-cyclic carbonates are enantioselectively hydrolyzed to afford the corresponding optically active syn-(2R,4R)-diols, although the hydrolysis of the cis-substrates gives racemic compounds In all cases, the enzyme prefers the (R)-enantiomer for the carbon atom bearing a Me group. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Product Details of 6413-10-1).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem