Chemical Research Letters, April 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. Category: dioxoles106-91-2, Name is Oxiran-2-ylmethyl methacrylate, SMILES is CC(C(OCC1OC1)=O)=C, belongs to dioxole compound. In a article, author is Anac, O, introduce new discover of the category.
Reactions of alpha,beta-enones with diazo compounds part 3 on the nature of the 1,5-ring closure of alpha,beta-enone ylides
Carbonyl ylides arising from ethyl acetodiazoacetate/dimethyl diazomalonate and a,beta-enones with mainly s-cis conformations underwent disrotatory cyclization to produce dihydrofuran derivatives. This process proved to be sensitive to steric effects. The corresponding ylides arising from rather s-trans a,beta-enals yielded dioxole derivatives. The mechanisms of the reactions are discussed.
Interested yet? Read on for other articles about 106-91-2, you can contact me at any time and look forward to more communication. Category: dioxoles.
Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem