On August 31, 1994, Mootoo, David; Wilson, Phyllis; Jammalamadaka, Vasu published an article.Recommanded Product: 38838-06-1 The title of the article was Application of the Keck radical coupling reaction to the preparation of allylated C5 furanosides and C6 pyranosides. And the article contained the following:
Allylated C5 furanosides, e.g. I, and C6 pyranosides, e.g. II, were prepared from known monosaccharide diol or polyol derivatives via a reaction sequence involving the initial selective formation of the primary iodide followed by application of the Keck allyl radical coupling reaction. Although the yields of the products in the coupling reaction were somewhat modest (usually 55-65%), the protocol was applicable to a variety of substrates, including sterically crowded cases, is exptl. simple and suitable for large scale preparations The experimental process involved the reaction of (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole(cas: 38838-06-1).Recommanded Product: 38838-06-1
The Article related to monosaccharide keck homolytic coupling, keck allylation iodination monosaccharide, glycoside pyranoside furanoside, Carbohydrates: Glycosides and other aspects.Recommanded Product: 38838-06-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem