On April 29, 2016, Mattis, Clayton E.; Mootoo, David R. published an article.COA of Formula: C9H15IO4 The title of the article was A ring closing metathesis strategy for carbapyranosides of xylose and arabinose. And the article contained the following:
The synthesis of β-carba-xylo and arabino pyranosides of cholestanol is described. The synthetic strategy, which is analogous to the Postema approach to C-glycosides, centers on the ring closing metathesis of an enol ether-alkene precursor to give a cyclic enol ether that is elaborated to a carba-pyranoside via hydroboration-oxidation on the olefin. The method, which is attractive for its modularity and stereoselectivity, may find wider applications to carba-hexopyranosides and other complex cycloalkyl ether frameworks. The experimental process involved the reaction of (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole(cas: 38838-06-1).COA of Formula: C9H15IO4
The Article related to c-glycosides role: rct (reactant), spn (synthetic preparation), ract (reactant or reagent), prep (preparation), cross-metathesis, disaccharides role: rct (reactant), spn (synthetic preparation), ract (reactant or reagent), prep (preparation), hydroboration, oxidation, ring-closing metathesis, steroidal glycosides role: rct (reactant), spn (synthetic preparation), ract (reactant or reagent), prep (preparation) and other aspects.COA of Formula: C9H15IO4
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem