Lu, Jingkun et al. published their research in Inorganic Chemistry in 2018 | CAS: 13818-44-5

(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Quality Control of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate

Facile CO2 Cycloaddition to Epoxides by Using a Tetracarbonyl Metal Selenotungstate Derivate [{Mn(CO)3}4(Se2W11O43)]8- was written by Lu, Jingkun;Ma, Xinyi;Singh, Vikram;Zhang, Yujiao;Wang, Ping;Feng, Junwei;Ma, Pengtao;Niu, Jingyang;Wang, Jingping. And the article was included in Inorganic Chemistry in 2018.Quality Control of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate This article mentions the following:

A novel polyoxometalate cluster, i.e., Na1.5H4.5[(CH3)4N]2{[Mn(CO)3]4(Se2W11O43)}·9H2O (1), has been successfully synthesized under moderately acidic conditions. Compound 1 contains four electron-donating {Mn(CO)3}+ organometallic entities, which are grafted over an unprecedented heteropolytungstate electron-acceptor group. Compound 1 was further structurally characterized by various physicochem. techniques like elemental analyses, inductively coupled plasma (ICP) analyses, IR and UV-vis spectroscopy, electrochem., and single-crystal X-ray diffraction, and so on. The polyoxoanion of 1 comprises a novel {Se2W11} fragment, which is obtained from mol. assembly of rare {SeW3} and {SeW8} species. Evaluation of the data from solution-state IR spectrum showed excellent agreement with the solid state IR spectrum, indicating the intact clusters in the CH3CN/Na2SO4 solvent. Also, neg. electrospray ionization mass spectrometry (ESI-MS) was an alternative tool to verify the stability of 1 in the mixed solvent. Addnl., the resulting hybrid can act as a catalyst for cyclic carbonate formation from the reactants epoxides and CO2 under modest reaction conditions in conjunction with a 1-ethyl-1-methylpyrrolidinium bromide (2). The good activity can be substantiated due to the cooperative influence of polyoxoanion and Br– ions. Complex 1 can also be easily recycled and reused three times without obvious decrease of catalytic activity. In the experiment, the researchers used many compounds, for example, (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5Quality Control of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate).

(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate (cas: 13818-44-5) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Quality Control of (2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem