(3aS,4S,6R,6aS)-6-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol (cas: 14131-84-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Category: dioxole
Total Synthesis of (-)-Orthodiffenes A and C was written by Liu, Jun;Liu, Yi;Zhang, Xing;Zhang, Chaoli;Gao, Yangguang;Wang, LinLin;Du, Yuguo. And the article was included in Journal of Organic Chemistry in 2012.Category: dioxole This article mentions the following:
The efficient and concise synthesis of (-)-orthodiffenes A (I) and C (II) has been accomplished for the first time in eight steps from readily available chiral synthons, D-mannose and D-Et lactate. Our work confirmed the complete structure of orthodiffenes A and C, including their absolute stereochem. The key steps of our total synthesis involved cis-fused THF cyclization, one-pot deprotection-lactonization, and intramol. benzoyl migration according to a biosynthetic hypothesis of orthodiffenes. In the experiment, the researchers used many compounds, for example, (3aS,4S,6R,6aS)-6-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol (cas: 14131-84-1Category: dioxole).
(3aS,4S,6R,6aS)-6-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol (cas: 14131-84-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Category: dioxole
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem