Introduction of a new synthetic route about 7524-52-9

Here is a brief introduction to this compound(7524-52-9)Category: dioxole, if you want to know about other compounds related to this compound(7524-52-9), you can read my other articles.

Category: dioxole. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: H-Trp-OMe.HCl, is researched, Molecular C12H15ClN2O2, CAS is 7524-52-9, about Biomimetic Enantioselective Total Synthesis of (-)-Robustanoids A and B and Analogues. Author is Liu, Zhan-Jiang; Huang, Pei-Qiang.

We report a step-economical, enantioselective total synthesis of (-)-robustanoid B, I (R = MeO), and (-)-robustanoid A, I (R = OH), and four novel natural product-like compounds Our strategy relied on our biosynthetic hypothesis and on a novel complexity generation methodol., namely, the one-pot hydroxylative double cyclization reaction. The latter consists of a modified 3,3-dimethyldioxirane-triggered epoxidation-epoxide-ring-opening cyclization reaction cascade and Trost’s regioselectivity umpolung methodol. (“”anti-Michael addition””).

Here is a brief introduction to this compound(7524-52-9)Category: dioxole, if you want to know about other compounds related to this compound(7524-52-9), you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem