As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves. SDS of cas: 91526-18-091526-18-0, Name is 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one, SMILES is CC1=C(CO)OC(=O)O1, belongs to dioxole compound. In a article, author is Sylvain, C, introduce new discover of the category.
In spite of early reports by Birch, we demonstrated that treatment of benzodioxoles with sodium in ammonia in the presence of methanol almost quantitatively yields the corresponding dihydro compounds. Despite their poor stability these compounds are synthetically useful. Treatment of 5-isobutyl-4,7-dihydrobenzo[1,3]dioxole with bromotrimethylsilane gives 6-hydroxy-3-isobutylcyclohex-2-enone in 80% yield. Treatment of 4,7-dihydrobenzo[1,3]dioxole with potassium in liquid ammonia in the presence of iron(III) chloride leads to 3a,4-dihydrobenzo[1,3]dioxole in high yield..
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem