Ikeda, Keiichi’s team published research in Synlett in 23 | CAS: 177-10-6

Synlett published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Name: 1,4-Dioxaspiro[4.5]decane.

Ikeda, Keiichi published the artcileRh(I)-Catalyzed cyclocarbonylation of enynes with glyceraldehyde: an available carbonyl source derived from sugar alcohols, Name: 1,4-Dioxaspiro[4.5]decane, the publication is Synlett (2012), 23(3), 393-396, database is CAplus.

Catalytic cyclocarbonylation reactions using a glyceraldehyde derivative as a carbonyl source are described. The rhodium(I)-catalyzed reaction of enynes, e.g., H2C:CHCH2OCH2CCR ( R = Ph, n-Bu, CMe3), with glyceraldehyde acetonide I gave bicyclic cyclopentenones, e.g., II, as the products. This presents an interesting use of a sugar alc. derived carbon resource as well as a convenient procedure for the cyclocarbonylation of enynes.

Synlett published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Name: 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem