He, Si-Qing published the artcilePreparation of carboxyethyltin group-functionalized highly ordered mesoporous organosilica composite material with double acid sites, Name: 1,4-Dioxaspiro[4.5]decane, the publication is Journal of Materials Science (2019), 54(6), 4601-4618, database is CAplus.
A series of highly ordered mesoporous ethane-bridged organosilica composite materials functionalized by carboxyethyltin group, SnR-Si(Et)Si-X (SnR and Si(Et)Si denote [Sn(CH2)2COOH]3+ and ethane-bridged organosilica groups, resp.), were successfully designed through one-step co-condensation-hydrothermal method. The pore morphol. and textural properties, Sn(IV) coordination environment, the type of acid site, Bronsted and Lewis acid strength were systematically characterized by LXRD, TEM observation, N2 porosimetry measurements, MAS NMR (29Si, 13C, 119Sn), UV-Vis diffuse reflectance spectrum, as well as 1H and 31P MAS NMR, FT-IR anal. of adsorbed pyridine, acid-base titration Composite materials SnR-Si(Et)Si-X possess Bronsted and Lewis acid sites, which originates from -COOH in [Sn(CH2)2COOH]3+ group and bridging OH in [Si(OH)SnR] group as well as tetrahedral coordination framework Sn(IV) in the open configuration [SnR(SiO)3(OH)], resp. The above 2D hexagonal mesoporous structure with unique textural properties, double acid sites (Bronsted and Lewis acid sites) and hydrophobic surface make SnR-Si(Et)Si-X exhibit excellent acid catalytic activity, reusability and water tolerance toward ketalization of cyclohexanone with glycol in absence of azeotrope agent at low temperature
Journal of Materials Science published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Name: 1,4-Dioxaspiro[4.5]decane.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem