Hallonquist, E. G. et al. published their research in Canadian Journal of Research in 1933 | CAS: 2568-30-1

2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C4H7ClO2

Reactions relating to carbohydrates and polysaccharides. XLIV. Synthesis of isomeric bicyclic acetal ethers was written by Hallonquist, E. G.;Hibbert, H.. And the article was included in Canadian Journal of Research in 1933.Computed Properties of C4H7ClO2 This article mentions the following:

3,5,7-Trioxabicyclo[2.2.2]octane (I), m. 99° and of high vapor pressure, results in 95% yield by the action of aqueous KOH at 100° on 1,3-bromoethylideneglycerol 2-benzoate ( Acid hydrolysis of I gives HOCH2CHO and glycerol, hydrolysis at the acetal ether linkages taking place simultaneously. Glycerol α-benzoate (II), prepared in 98% yield (Fischer, Bergmann and Barwind, C. A. 15, 684), treated with tribromoparaldehyde gives 1,2-bromoethylideneglycerol 3-benzoate (III). III with aqueous KOH gives 3,6,8-trioxabicyclo[3.2.1]octane (IV), m. 56-7° and of high vapor pressure. III in this reaction compared with its isomer is fairly inert. IV on hydrolysis gives HOCH2CHO and glycerol. I and IV show no indication of interconvertibility on solution in solvents or under the influence of heat (Haskelberg, C. A. 26, 3777). Glycerol (30 g.) and ClCH2CH(OEt)2 (50 g.), heated with stirring at 115° for 15 min., gave on distilling chloroethylideneglycerol, b13, 130-4°, in 80% yield. Similarly there was prepared chloroethylideneglycol, b13 57°, chloroethylidenetrimethylene glycol, b11 60-2°, β-chloropropylideneglycerol, b15 129-35°, and β-bromopropylideneglycerol, b18 136-40°, in yields of 40, 60, 56 and 65%, resp. The application of this method to the synthesis of cyclic acetals from open-chain acetals is being used in the determination of the structure of carbohydrates and polysaccharides. In the experiment, the researchers used many compounds, for example, 2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1Computed Properties of C4H7ClO2).

2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C4H7ClO2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem