On March 21, 1994, Gallos, John K.; Koftis, Theocharis V.; Koumbis, Alexandros E. published an article.Recommanded Product: 38838-06-1 The title of the article was Synthesis of enantiomerically pure bicyclo[3.1.0]hexanes from D-ribose by intramolecular cyclopropanation. And the article contained the following:
Highly functionalized optically pure bicyclo[3.1.0]hexan-2-ones I were easily obtained by the intramol. cyclopropanation of a D-ribose derivative using the iodonium ylide or diazo compound methods, which afford the final products with opposite diastereoselectivities. The derivatives of the title compounds are Et 2,2-dimethyl-5-oxocyclopropa[3,4]cyclopenta[1,2-d]-1,3-dioxole-4a-carboxylates. The experimental process involved the reaction of (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole(cas: 38838-06-1).Recommanded Product: 38838-06-1
The Article related to cyclopropanation ribose iodonium ylide, dioxolanepropanoate vinyl oxo cyclopropanation, cyclopropacyclopentadioxolecarboxylate asym synthesis, Heterocyclic Compounds (More Than One Hetero Atom): Eight- and Higher-Membered Rings and other aspects.Recommanded Product: 38838-06-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem