Pd-catalyzed tandem homocoupling-aldol-dehydration of ortho-acylphenyl iodides was written by Fu, Meiqin;Lin, Dongen;Deng, Yuanfu;Zhang, Xiao-Qi;Liu, Yanchu;Lai, Chunsong;Zeng, Wei. And the article was included in RSC Advances in 2014.Computed Properties of C9H9NO3 This article mentions the following:
Syntheses of substituted dibenzo[a,c][7]annulen-5-ones, e.g. I, were carried out by Pd-catalyzed Ullmann homo-coupling between two mols. of ortho-acylphenyl iodides followed by intramol. aldol dehydration in presence of K2CO3 in DMF. This transformation provided a concise access to colchino analogs in moderate to good yields with wide functional group tolerance. In the experiment, the researchers used many compounds, for example, 1-(6-Aminobenzo[d][1,3]dioxol-5-yl)ethanone (cas: 28657-75-2Computed Properties of C9H9NO3).
1-(6-Aminobenzo[d][1,3]dioxol-5-yl)ethanone (cas: 28657-75-2) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C9H9NO3
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem