Vibrational circular dichroism and absolute configuration of 1-substituted indans was written by Fontana, Luca P.;Chandramouly, Tummalapalli;Smith, Howard E.;Polavarapu, Prasad L.. And the article was included in Journal of Organic Chemistry in 1988.Electric Literature of C10H11BrO2 This article mentions the following:
Vibrational CD (VCD) spectra of title compounds (R)- and (S)-I (R = NH2, R1 = H), (S)-I (R = Me, R1 = H), and (R)-I (R = Me, R1 = D) were measured at 800-1600 cm-1. The VCD feature associated with the C*-H bending mode at ∼1350 cm-1 correlated with their absolute configurations. This correlation agrees with one found for (S)-methyloxirane and (R)-methylthiirane, and reflects the potential importance of VCD measurements in stereochem. anal. of chiral rings systems. In the experiment, the researchers used many compounds, for example, 2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1Electric Literature of C10H11BrO2).
2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Electric Literature of C10H11BrO2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem