Related Products of 707-61-9. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Novel synthesis and structure of phosphanyl sugar derivatives. Author is Yamashita, Mitsuji; Yabui, Akihiro; Suzuki, Kazumitsu; Kato, Yukihiro; Uchimura, Miyuki; Iida, Akihito; Mizuno, Hiroyuki; Ikai, Koichi; Oshikawa, Tatsuo; Parkanayi, Laszlo; Clardy, Jon.
Some phosphanyl sugars, e.g. I, which are analogs of sugars having a phosphorus atom in place of the ring oxygen, were synthesized from 2- and 3-phospholenes as starting materials. Catalytic cis-dihydroxylation of 2-phospholene or 3-phospholene 1-oxide derivatives with osmium(VIII) oxide in the presence of a Co-oxidant afforded 3-deoxy- or 1-deoxy-tetrofuranose-type phosphanyl sugar derivatives, resp. Cis-Dihydroxylation of 4-acyloxy-2-phospholene 1-oxide derivatives gave tetrofuranose type phosphanyl sugar derivatives Some of these derivatives of phosphanyl sugars were subjected to structural analyses using 1H NMR and X-ray crystallog.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem