New Advances in Chemical Research, April 2021. Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. 54623-25-5, Name is 2,3,5-Tri-O-benzyl-D-ribose, SMILES is O=C[C@@H]([C@@H]([C@@H](COCC1=CC=CC=C1)O)OCC2=CC=CC=C2)OCC3=CC=CC=C3, belongs to dioxole compound. In a document, author is Wang, XY, introduce the new discover, Application In Synthesis of 2,3,5-Tri-O-benzyl-D-ribose.
Two very permeable polymers, poly(1-trimethylsilyl-1-propyne) (PTMSP) and a random copolymer of tetrafluoroethylene and 2.2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (TFE/BDD), have very similar and large fractional free volumes (FFV), but very different permeabilities. Using atomistic models, cavity size (free volume) distributions determined by a combination of molecular dynamic and Monte Carlo methods are consistent with the observation that PTMSP is more permeable than TFE/BDD. The average spherical cavity size in PTMSP is 11.2 Angstrom whereas it is only 8.2 Angstrom in TFE/BDD. These cavity size distributions determined by simulation are also consistent with free volume distributions determined by positron annihilation lifetime spectroscopy. (C) 2004 Published by Elsevier Ltd.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem