Chemical reactivity and safener activity of acetal compounds was written by Ekler, Zsigmond;Dutka, Ferenc. And the article was included in Zeitschrift fuer Naturforschung, C: Journal of Biosciences in 1991.SDS of cas: 2568-30-1 This article mentions the following:
The chem. reactivity of acetamide-type compounds as well as their safener activity against thiocarbamate herbicides change with the number of chlorine substituents in the order: nonchlorinated < monochloro < dichloro. Several compounds of another chem. group, acetal (e.g., MG-191, 2-dichloromethyl-2-methyl-1,3-dioxolane), are also effective safeners for thiocarbamate herbicides. According to growthroom studies, the safener activity of acetals also increases with increasing chlorine content up to two chlorine atoms on the same carbon. A number of differently chlorinated acetals were synthesized and their acid-catalyzed hydrolysis rate determined in order to establish a relationship between their bioactivity and chem. reactivity. The hydrolysis rate order of acetals (nonchlorinated > monochloro > dichloro) is the opposite of that found for acetamides. Thus, safener activity of acetals increases with decreasing chem. reactivity. The opposite reactivity order of acetamides and acetals can be explained by the different mechanisms of their hydrolysis. Dichloroacetals are not effective safeners without further modification. In plants, however, they may be activated by a nonhydrolytic pathway. In the experiment, the researchers used many compounds, for example, 2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1SDS of cas: 2568-30-1).
2-Chloromethyl-1,3-dioxolane (cas: 2568-30-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.SDS of cas: 2568-30-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem