In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Trimethyl Orthoacetate and Ethylene Glycol Mono-Vinyl Ether as Enolate Surrogates in Enantioselective Iridium-Catalyzed Allylation, published in 2018, which mentions a compound: 1265884-98-7, mainly applied to trimethyl orthoacetate allylic carbonate iridium catalyst enantioselective allylation; unsaturated ester stereoselective preparation; ethyleneglycol vinyl ether allylic carbonate iridium catalyst enantioselective allylation; protected aldehyde stereoselective preparation; conical formal enantioselective synthesis; allylation; asymmetric catalysis; iridium; total synthesis; trimethyl orthoacetate, SDS of cas: 1265884-98-7.
Tri-Me orthoacetate and ethylene glycol mono-vinyl ether are employed in iridium-catalyzed enantioselective allylation reactions. The method documented enables their convenient use as surrogates for silyl ketene acetals and silyl enol ethers to prepare γ,δ-unsaturated esters and protected aldehydes with excellent enantioselectivity. The utility of this novel method has been demonstrated by its implementation in a formal enantioselective synthesis of the meroterpenoid (+)-conicol.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem