Study on catalytic synthesis of fructone was written by Deng, Bin;Zhang, Aihua;Xu, Anwu. And the article was included in Shangqiu Shifan Xueyuan Xuebao in 2009.Reference of 6413-10-1 The following contents are mentioned in the article:
Microwave irradiation was used in the catalytic synthesis of fructone from Et acetoacetate and ethanol using nanometer Y2O3 as a catalyst. The influence of microwave irradiation power, microwave irradiation time, mole ratio of ethanol to Et acetoacetate, and the dosage of the catalyst on the reaction was investigated. The optimum reaction conditions determined through orthogonal design were as follows: microwave irradiation power was 400 W, microwave irradiation time 9 min, the mole ratio of ethanol to Et acetoacetate was 1.2 : 1 and the dosage of the catalyst was 2.0 g. Under the optimum reaction conditions the yield of fructone was above 95 %. In summary, the microwave technique promotes the synthesis of fructone with high yield and convenient operation and has extensive utilization. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Reference of 6413-10-1).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Reference of 6413-10-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem